Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.
نویسندگان
چکیده
Cofacial Fe2, Co2, and Ni2 complexes supported by a para-terphenyl diphosphine ligand were prepared. Central arene deplanarization and a μ2:(η(3),η(3)) coordination mode suggest partial bisallyl character in the Fe2 and Co2 complexes. An oxidation induced shift in Fe2-arene binding highlights the non-innocent nature of the arene ligand.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 34 شماره
صفحات -
تاریخ انتشار 2014